I’ve always struggled with it, there seems to be a time of year (late spring, summer and early fall) where the afternoon minimum dew point reading works really well at MVL for low temps. Like it’ll nail it spot on to what that minimum afternoon dew is.
However now in the season of longer darkness at night, it seems to exceed that afternoon dew point by quite a bit at times (ie afternoon dew is 40F, the next morning can be 32F now...but in late August if the dew is 40F the next morning temp will be 40F).
Ive always attributed it to the length of night (ie extra hours of rad cooling) but I’ve always wondered about the mechanics of how it can be 38/38 at 8pm, but keep dropping to be 28/28 by 6am. It’s like the dews and temps come down together once they meet.